Diffusion Activation Energy and Desorption Activation Energy for Astrochemically Relevant Species on Water Ice Show No Clear Relation
نویسندگان
چکیده
Abstract The activation energies for desorption ( E des ) and surface diffusion sd of adsorbed molecules on dust grains are two the most important parameters chemistry in interstellar medium. Although is often measured by laboratory experiments, measurement sparse. Due to lack data, astrochemical models usually assume a simple scaling relation, = f , where constant, irrespective species. Here, we experimentally measure CH 4 H 2 S, OCS, 3 OH, CN water-ice surfaces using an ultrahigh-vacuum transmission electron microscope. Compiling values from literature, find that value ranges ∼0.2 ∼0.7, depending Unless (or majority species available, natural alternative approach running multiple simulations, varying each randomly. In this approach, molecular abundances predicted rather than simulation, important. We here run 10,000 simulations clouds protostellar envelopes, randomly assigning former case, identify several key whose strongly affects uncertainties model predictions; those should be investigated future quantum chemical studies. latter many contribute predictions.
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ژورنال
عنوان ژورنال: The astrophysical journal
سال: 2022
ISSN: ['2041-8213', '2041-8205']
DOI: https://doi.org/10.3847/2041-8213/ac78e9